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Polystyrene (PS)

Product Code : CE-PS-NN-CU

Polystyrene (PS)is a synthetic polymer made from monomers of the aromatic hydrocarbon styrene. Polystyrene can be solid or foamed. General-purpose polystyrene is clear, hard, and brittle. It is an inexpensive resin per unit weight. It is a poor barrier to oxygen and water vapor and has a relatively low melting point. Polystyrene is one of the most widely used plastics, the scale of its production being several million tonnes per year. Polystyrene can be naturally transparent, but can be colored with colorants. Uses include protective packaging (such as packing peanuts and in the jewel cases used for storage of optical discs such as CDs and occasionally DVDs), containers, lids, bottles, trays, tumblers, disposable cutlery, in the making of models, and as an alternative material for phonograph records. As a thermoplastic polymer, polystyrene is in a solid (glassy) state at room temperature but flows if heated above about 100 °C, its glass transition temperature. It becomes rigid again when cooled. This temperature behaviour is exploited for extrusion (as in Styrofoam) and also for molding and vacuum forming, since it can be cast into molds with fine detail. Under ASTM standards, polystyrene is regarded as not biodegradable. It is accumulating as a form of litter in the outside environment, particularly along shores and waterways, especially in its foam form, and in the Pacific Ocean.


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Polystyrene (PS) CE-PS-NN-CU Customized Customized

Product Information

Polystyrene (PS)is a synthetic polymer made from monomers of the aromatic hydrocarbon styrene. Polystyrene can be solid or foamed. General-purpose polystyrene is clear, hard, and brittle. It is an inexpensive resin per unit weight. It is a poor barrier to oxygen and water vapor and has a relatively low melting point. Polystyrene is one of the most widely used plastics, the scale of its production being several million tonnes per year. Polystyrene can be naturally transparent, but can be colored with colorants. Uses include protective packaging (such as packing peanuts and in the jewel cases used for storage of optical discs such as CDs and occasionally DVDs), containers, lids, bottles, trays, tumblers, disposable cutlery, in the making of models, and as an alternative material for phonograph records. As a thermoplastic polymer, polystyrene is in a solid (glassy) state at room temperature but flows if heated above about 100 °C, its glass transition temperature. It becomes rigid again when cooled. This temperature behaviour is exploited for extrusion (as in Styrofoam) and also for molding and vacuum forming, since it can be cast into molds with fine detail. Under ASTM standards, polystyrene is regarded as not biodegradable. It is accumulating as a form of litter in the outside environment, particularly along shores and waterways, especially in its foam form, and in the Pacific Ocean.

In chemical terms, polystyrene is a long chain hydrocarbon wherein alternating carbon centers are attached to phenyl groups (a derivative of benzene). Polystyrene's chemical formula is (C8H8)n; it contains the chemical elements carbon and hydrogen. The material's properties are determined by short-range van der Waals attractions between polymers chains. Since the molecules consist of thousands of atoms, the cumulative attractive force between the molecules is large. When heated (or deformed at a rapid rate, due to a combination of viscoelastic and thermal insulation properties), the chains can take on a higher degree of confirmation and slide past each other. This intermolecular weakness (versus the high intramolecular strength due to the hydrocarbon backbone) confers flexibility and elasticity. The ability of the system to be readily deformed above its glass transition temperature allows polystyrene (and thermoplastic polymers in general) to be readily softened and molded upon heating. Extruded polystyrene is about as strong as an unalloyed aluminium but much more flexible and much less dense (1.05 g/cm3 for polystyrene vs. 2.70 g/cm3 for aluminium)

Synonyms

Poly(1-phenylethylene), Thermocol


Polystyrene (PS) Specification

Size:customized

Purity: customized

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Properties(Theoretical)

Chemical formula(C8H8)n
Dielectric constant @1MHz2-3
Dielectric strength ( kV mm⁻¹ )20
Dissipation factor @ 1kHz0.0002
Volume resistivity ( Ohmcm )>10¹⁶
Elongation at break ( % )1.6
Hardness - RockwellM60-90
Izod impact strength ( J m⁻¹ )19.0 - 24.0
Poisson's ratio0.35
Tensile modulus ( GPa )2.30 - 4.10
Tensile strength ( MPa )30.00 - 100.00
Abbe number30.8
Density ( g cm⁻³ )1.05
FlammabilityHB
Limiting oxygen index ( % )19
Radiation resistanceGood
Refractive index1.590-1.600
Resistance to Ultra-violetPoor
Water absorption - over 24 hours ( % )< 0.400
Coefficient of thermal expansion ( x10⁻⁶ K⁻¹ )30.000 - 210.000
Heat-deflection temperature - 0.45MPa ( C )90
Heat-deflection temperature - 1.8MPa ( C )80
Specific heat ( J K⁻¹ kg⁻¹ )1200
Thermal conductivity ( W m⁻¹ K⁻¹ )0.10 - 0.13 @23°C
Upper working temperature ( C )50 - 95
Permeability to Carbon Dioxide @25C ( x10⁻¹³ cm³. cm cm⁻² s⁻¹ Pa⁻¹ )8
Permeability to Water @38C ( x10⁻¹³ cm³. cm cm⁻² s⁻¹ Pa⁻¹ )800
Melting point~ 240 °C (464 °F; 513 K) for isotactic polystyrene
Boiling point430 °C (806 °F; 703 K) and depolymerizes
Solubility in waterInsoluble
SolubilitySoluble in benzene, carbon disulfide, chlorinated aliphatic   hydrocarbons, chloroform, cyclohexanone, dioxane, ethyl acetate,   ethylbenzene, MEK, NMP, THF


Chemical Resistance

Acids - concentratedFair-Poor
Acids - diluteGood-Fair
AlcoholsGood-Fair
AlkalisGood-Fair
Aromatic hydrocarbonsPoor
Greases and OilsGood-Poor
Halogenated HydrocarbonsPoor
HalogensPoor
KetonesPoor





Applications of Polystyrene (PS)

Polystyrene (PS) is used for producing disposable plastic cutlery and dinnerware, CD "jewel" cases, smoke detector housings, license plate frames, plastic model assembly kits, and many other objects where a rigid, economical plastic is desired. Production methods include thermoforming (vacuum forming) and injection molding. Polystyrene Petri dishes and other laboratory containers such as test tubes and microplates play an important role in biomedical research and science. For these uses, articles are almost always made by injection molding, and often sterilized post-molding, either by irradiation or by treatment with ethylene oxide. Post-mold surface modification, usually with oxygen-rich plasmas, is often done to introduce polar groups. Much of modern biomedical research relies on the use of such products; they, therefore, play a critical role in pharmaceutical research. Thin sheets of polystyrene are used in polystyrene film capacitors as it forms a very stable dielectric, but has largely fallen out of use in favor of polyester.


Packing of Polystyrene (PS)

Standard Packing:

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes Special package is available on request.

ATTs’ Polystyrene (PS) is carefully handled to minimize damage during storage and transportation and to preserve the quality of our products in their original condition.

 

Chemical Identifiers

CAS Number9003-53-6
AbbreviationsPS
ChemSpidernone
ECHA InfoCard100.105.519
CompTox Dashboard (EPA)DTXSID5031925



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